Measuring individual overpotentials in an operating solid-oxide electrochemical cell

Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy.

Photoelectron spectroscopic measurements have the potential to provide detailed mechanistic insight by resolving chemical states, electrochemically active regions and local potentials or potential losses in operating solid oxide electrochemical cells (SOCs), such as fuel cells. However, high-vacuum requirements have limited X-ray photoelectron spectroscopy (XPS) analysis of electrochemical cell...

An octane-fueled solid oxide fuel cell.

There are substantial barriers to the introduction of hydrogen fuel cells for transportation, including the high cost of fuel-cell systems, the current lack of a hydrogen infrastructure, and the relatively low fuel efficiency when using hydrogen produced from hydrocarbons. Here, we describe a solid oxide fuel cell that combines a catalyst layer with a conventional anode, allowing internal refor...

In Situ X-ray and Electrochemical Studies of Solid Oxide Fuel Cell / Electrolyzer Oxygen Electrodes

The governing reaction mechanisms, and the electrode material compositions and structures, that controls the efficiency of the solid oxide fuel cells (SOFC) and solid oxide electrolysis cells (SOEC) need to be identified and well-understood for significant technological improvements. Our study on the oxygen electrodes focuses on specifically the effect of electrode crystal structure and morphol...

Strategies for Lowering Solid Oxide Fuel Cells Operating Temperature

Lowering the operating temperature of solid oxide fuel cells (SOFCs) to the intermediate range (500–700 oC) has become one of the main SOFC research goals. High operating temperatures put numerous requirements on materials selection and on secondary units, limiting the commercial development of SOFCs. The present review first focuses on the main effects of reducing the operating temperature in ...

Electrochemical Impedance Spectroscopy Study of the Mass Transfer in an Anode-Supported Microtubular Solid Oxide Fuel Cell